XIN Yang,GUO Peng,LI Hao,CHEN Ren-de,SUN Li-li,MA Guan-shui,WANG Ai-ying.Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells[J],49(6):22-33 |
Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells |
Received:April 29, 2020 Revised:June 20, 2020 |
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DOI:10.16490/j.cnki.issn.1001-3660.2020.06.003 |
KeyWord:proton exchange membrane fuel cell bipolar plate carbon-based film conductivity corrosion resistance |
Author | Institution |
XIN Yang |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China; 2.Nano Science and Technology Institute, University of Science and Technology of China, Suzhou , China |
GUO Peng |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China |
LI Hao |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China |
CHEN Ren-de |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China |
SUN Li-li |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China |
MA Guan-shui |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China |
WANG Ai-ying |
1.a.Key Laboratory of Marine Materials and Related Technologies, b.Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Science, Ningbo , China; 3.Research Center of Materials and Photoelectricity, University of Chinese Academy of Sciences, Beijing , China |
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Abstract: |
In this work, the performances of bare metallic plate, traditional graphite plate and metallic bipolar plate modified with carbon-based coating used in the proton exchange membrane fuel cells (PEMFCs) were compared; the latest achievements of carbon-based coatings in improving the conductivity and corrosion resistance of metallic bipolar plates were reviewed; and issues such as performance degradation and limited life of carbon-based coatings were discussed, especially after long-term operation in PEMFCs environment. By analyzing the factors that affect the performance of carbon-based coatings, it was found that systematic researches on the relationship between microstructure of carbon-based coating and its performance were insufficient, leading to an unclear damage and degradation mechanism of a-C carbon coating/ metallic bipolar plate. The research progress of modified carbon-based coating materials for PEMFCs metal plates at home and abroad was mainly discussed, including improving the coating performance by adjusting the microstructure of carbon-based coatings (a-C); preparing metal-doped carbon coating (a-C:Me) by combing theoretical calculation with practice; solving the poor adhesion, high pressure stress and other issues between coating and special metallic matrix, design multi-layer structures to reduce penetrability defects. The failure mechanism of several kinds of coatings was discussed and the development trend of carbon-based coating technology for metallic plate modification was prospected. |
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