YANG Xia-qiong,CHEN Chao-yi,LI Jun-qi,QUAN Bian-li,LIU Li,LU Xiao-yu.Effect of Sodium Thiosulfate on Corrosion Behavior of 16Mn Steel in Sodium Aluminate Solution[J],45(6):173-179
Effect of Sodium Thiosulfate on Corrosion Behavior of 16Mn Steel in Sodium Aluminate Solution
Received:January 03, 2016  Revised:June 20, 2016
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DOI:10.16490/j.cnki.issn.1001-3660.2016.06.026
KeyWord:thiosulfate  16Mn steel  polarization curve  sodium aluminate solution  salt spray corrosion
                 
AuthorInstitution
YANG Xia-qiong 1.School of Material and Metallurgy, Guizhou University, Guiyang , China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang , China
CHEN Chao-yi 1.School of Material and Metallurgy, Guizhou University, Guiyang , China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang , China
LI Jun-qi 1.School of Material and Metallurgy, Guizhou University, Guiyang , China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang , China
QUAN Bian-li 1.School of Material and Metallurgy, Guizhou University, Guiyang , China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang , China
LIU Li 1.School of Material and Metallurgy, Guizhou University, Guiyang , China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang , China
LU Xiao-yu 1.School of Material and Metallurgy, Guizhou University, Guiyang , China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang , China
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Abstract:
      Objective To investigate the corrosion behavior of 16Mn steel in sodium aluminate solution with different S2O32? concentrations. Methods The corrosion behavior of 16Mn steel was studied by salt spray corrosion, weight loss method, electrochemical corrosion test and analyzed by SEM, EDS. Results Corrosion rate was raised from 0.4990 g/(m2·d) to 0.5180 g/(m2·d) and the maximum pitting depth rose from 3.6 μm to 4.5 μm, when the concentration of S2O32? increased from 3 g/L to 7 g/L, while the corrosion current density rose from 0.648 μA/cm2 to 5.186 μA/cm2 and the radius of capacitive arc decreased gradually. According to EDS analysis, corrosion products were composed of four elements (O, Al, S, Fe), the contents of Al, O were higher than those of the other elements and decreased after increased first with increase of S2O32? concentration. Conclusion Existence of thiosulfate accelerated corrosion of 16Mn steel in sodium aluminate solution. Corrosion behavior of 16Mn steel was notably affected by the changing concentration of S2O32?. Corrosion rate showed a trend of escalation with the increase of S2O32? concentration. Corrosion rate increased slowly in 3 g/L S2O32? for matrix protected by Al(OH)3 coatings on the surface of sample. The oxidation coating was penetrated by S2O32? after the S2O32? concentration increased to 4 g/L, and the corrosion rate increased relatively fast. However, the corrosion rate increased slowly and tended to be stable after the concentration of S2O32? increased to 5 g/L.
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