YE San-nan,WANG Pei,SUN Yang-chao,WANG Xiu-min,LI Chun-ling,HU Song-qing.Research Advances in Microcapsuled Self-healing Coatings Materials[J],45(6):91-99
Research Advances in Microcapsuled Self-healing Coatings Materials
Received:January 23, 2016  Revised:June 20, 2016
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DOI:10.16490/j.cnki.issn.1001-3660.2016.06.014
KeyWord:self-healing coating  microcapsule  polymer composites  self-healing property  corrosion resistance
                 
AuthorInstitution
YE San-nan Jianghan Oil Production Plant, Jianghan Oilfield Branch of Sinopec Group, Qianjiang , China
WANG Pei Material Physics and Chemistry, College of Science, China University of Petroleum, Qingdao , China
SUN Yang-chao Material Physics and Chemistry, College of Science, China University of Petroleum, Qingdao , China
WANG Xiu-min Material Physics and Chemistry, College of Science, China University of Petroleum, Qingdao , China
LI Chun-ling Material Physics and Chemistry, College of Science, China University of Petroleum, Qingdao , China
HU Song-qing Material Physics and Chemistry, College of Science, China University of Petroleum, Qingdao , China
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Abstract:
      Microcapsuled self-healing polymer is one of the hottest research topics in recent years. This paper summarized the repair mechanism of microcapsuled self-healing coatings. The common self-healing systems including dicyclopentadiene-Grubbscuring agent, epoxy resin-curing agent, polar solvent-epoxy resin, etc. were also introduced, from the aspects of their components, the stability of the microcapsule, the current research status and future development prospects. The preparation methods of microcapsule such as in-situ polymerization and interfacial polymerization were introduced as well. Meanwhile, the principle, characteristics, application scope of each preparation method, and their advantages and disadvantages were introduced. This paper also summarized the evaluation methods of the self-healing coating performances (mechanical properties and corrosion resistance). Self-healing microcapsule could recover 90% of the coating fracture toughness and 87% of coating adhesion between the layers. Electrochemical experiments indicated that microcapsuled self-healing coatings had better corrosion resistance compared with common coatings through measuring corrosion current and impedance. In addition, the repair progress of self-healing coatings could be explained through electrochemical experiments. At last, the applications of self-healing coatings were summarized, as well as the research trends of this filed.
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