林潼,杜蓉,郑晓军,殷绿,肖航,武元鹏,王勤英,张进.Fe3O4-MoS2协同改性环氧树脂涂层的制备及耐磨防腐性能研究[J].表面技术,2024,53(20):102-117.
LIN Tong,DU Rong,ZHENG Xiaojun,YIN Lyu,XIAO Hang,WU Yuanpeng,WANG Qinying,ZHANG Jin.Fe3O4-MoS2 Nanohybrid for Enhancing Wear Resistance and Anticorrosion Performance of Epoxy Coatings[J].Surface Technology,2024,53(20):102-117
Fe3O4-MoS2协同改性环氧树脂涂层的制备及耐磨防腐性能研究
Fe3O4-MoS2 Nanohybrid for Enhancing Wear Resistance and Anticorrosion Performance of Epoxy Coatings
投稿时间:2023-11-02  修订日期:2024-01-27
DOI:10.16490/j.cnki.issn.1001-3660.2024.20.009
中文关键词:  Fe3O4  MoS2  Fe3O4-MoS2纳米杂化物  环氧树脂  防腐耐磨
英文关键词:Fe3O4  MoS2  Fe3O4-MoS2 nanohybrid  epoxy resin  anticorrosive and wear-resistant
基金项目:四川省科技厅重点研发计划项目(2022YFG0368)
作者单位
林潼 西南石油大学 新能源与材料学院,成都 610500 
杜蓉 西南石油大学 新能源与材料学院,成都 610500 
郑晓军 西南石油大学 新能源与材料学院,成都 610500 
殷绿 中国科学院成都有机化学有限公司,成都 610041 
肖航 中国科学院成都有机化学有限公司,成都 610041 
武元鹏 西南石油大学 新能源与材料学院,成都 610500 
王勤英 西南石油大学 新能源与材料学院,成都 610500 
张进 西南石油大学 新能源与材料学院,成都 610500 
AuthorInstitution
LIN Tong School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China 
DU Rong School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China 
ZHENG Xiaojun School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China 
YIN Lyu Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China 
XIAO Hang Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China 
WU Yuanpeng School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China 
WANG Qinying School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China 
ZHANG Jin School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China 
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中文摘要:
      目的 解决油气装备管道面临的腐蚀磨损等失效问题。方法 使用不同物质的量比的纳米Fe3O4、MoS2通过硅烷偶联剂(APTES)结合为杂化填料,并将其填充至环氧树脂(EP)中,制备出复合涂层。利用扫描电镜(SEM)、X射线衍射仪(XRD)及傅里叶红外光谱(FT-IR)对杂化填料的显微结构、物相组成及成分进行了分析。同时,利用分散稳定性试验、显微维氏硬度、往复摩擦试验、表面轮廓测试、吸水率及接触角测试、电化学阻抗谱及动电位极化曲线综合评价复合涂层耐磨及防腐蚀性能。结果 Fe3O4-MoS2纳米杂化物在环氧树脂中具有良好的分散稳定性。与Fe3O4/EP、MoS2/EP相比,Fe3O4-MoS2/EP复合涂层的显微硬度与耐磨性提高,同时其耐水性和防腐性能也得到增强。当Fe3O4-MoS2物质的量比为1∶5时,复合涂层摩擦因数最低为0.337,相比于纯EP降低34.56%。当Fe3O4-MoS2物质的量比为1∶1,复合涂层阻抗值最高,并且显示出最大的腐蚀电位(Ecorr)和最小的腐蚀电流(Jcorr),Fe3O4-MoS2/EP涂层的阻抗(Rc)提高了近2个数量级。结论 Fe3O4-MoS2是可用于制备高性能环氧耐磨防腐涂料的有效的纳米填料。复合涂料优异的减摩性得益于Fe3O4颗粒的纳米球滚动润滑效应和MoS2片的滑移效应,而其高防腐性能归功于Fe3O4-MoS2良好的分散性和阻隔性。
英文摘要:
      To improve the low corrosion and wear resistance caused by micro-pores in epoxy resin, nano-Fe3O4 was used as a filler to modify the epoxy resin. However, considering the poor dispersion and easy aggregation of the nano-Fe3O4 filler, this study used a silane coupling agent (APTES) to modify Fe3O4 and connect it to the lubricating layered molybdenum disulfide. Q235 steel was used as the substrate, polished and cleaned with sandpaper, and 1 wt.% Fe3O4-MoS2 with different molar ratios (3 : 1, 1 : 1, 1 : 3, 1 : 5 and 1 : 7) was added to the epoxy resin to prepare composite coatings. The microstructure and phase composition of the hybrid filler were analyzed by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (Nicolet 6700). The dispersion of the filler in the epoxy resin was observed with a stereomicroscope (OM), and the microhardness of the coating was tested with a micro Vickers hardness tester (HV-1000STA). Wear tests were conducted on the surface multifunctional testing machine (MFT-4000), and the morphology of wear marks was observed and elemental analysis was performed. The corrosion resistance of the coating was comprehensively evaluated by water absorption rate, contact angle test, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization tests.
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