范维新,蒲长庚,罗思海,何卫锋,梁晓晴,臧顺来.无保护层激光强化对316L/Inc600焊接接头焊缝部位耐腐蚀性的影响[J].表面技术,2024,53(20):51-60.
FAN Weixin,PU Changgeng,LUO Sihai,HE Weifeng,LIANG Xiaoqing,ZANG Shunlai.Effect of Laser Peening Without Coating on Corrosion Resistance of the Weld Area of 316L/Inc600 Welded Joint[J].Surface Technology,2024,53(20):51-60 |
| 无保护层激光强化对316L/Inc600焊接接头焊缝部位耐腐蚀性的影响 |
| Effect of Laser Peening Without Coating on Corrosion Resistance of the Weld Area of 316L/Inc600 Welded Joint |
| 投稿时间：2023-10-30 修订日期：2024-04-04 |
| DOI：10.16490/j.cnki.issn.1001-3660.2024.20.004 |
| 中文关键词: 无吸收保护层激光冲击强化 微观组织 异种金属焊接 电化学腐蚀 腐蚀形貌 |
| 英文关键词:laser peening without coating microstructure dissimilar welding electrochemical corrosion corrosion morphology |
| 基金项目:国家自然科学基金(52375225) |
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| Author | Institution |
| FAN Weixin | National Key Lab of Aerospace Power System and Plasma Technology,Institute of Aeronautics Engine, School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an 710049, China |
| PU Changgeng | National Key Lab of Aerospace Power System and Plasma Technology,Institute of Aeronautics Engine, School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an 710049, China;AECC Aero Science and Technology Co., Ltd., Chengdu 610000, China |
| LUO Sihai | National Key Lab of Aerospace Power System and Plasma Technology, Air Force Engineering University, Xi'an 710038, China |
| HE Weifeng | National Key Lab of Aerospace Power System and Plasma Technology,Institute of Aeronautics Engine, School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an 710049, China;National Key Lab of Aerospace Power System and Plasma Technology, Air Force Engineering University, Xi'an 710038, China |
| LIANG Xiaoqing | National Key Lab of Aerospace Power System and Plasma Technology, Air Force Engineering University, Xi'an 710038, China |
| ZANG Shunlai | National Key Lab of Aerospace Power System and Plasma Technology,Institute of Aeronautics Engine, School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an 710049, China |
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| 中文摘要: |
| 目的 获得无吸收保护层激光冲击强化(LPwC，Laer Peening without Coating)对316L/Inc 600异种金属焊接接头焊缝部位耐腐蚀性能的影响机理。方法 对316L/Inc 600焊缝部位进行无吸收保护层的激光冲击强化处理，采用光学显微镜、扫描电子显微镜和共聚焦显微镜对不同强化工艺下焊缝部位的形貌和元素分布进行观察。用电化学工作站测试不同工艺下焊缝部位的交流阻抗谱和动电位极化曲线。对电化学测试后的焊缝进行形貌观察和能谱检测。结果 LPwC后在金属表层引入厚度约0.54 μm的重熔层，粗糙度从96 nm增加到691 nm。强化处理和打磨处理后焊缝的电荷转移电阻分别为原始样品的1.7倍和3.1倍，钝化电流减小1~2个数量级，点蚀电位增加100 mV以上。强化处理后的点蚀坑平均直径从原始样品的33.41 μm减小到17.20 μm，体积损失从122 886 μm3降为49 068 μm3，且内部无元素偏析和碳化物。原始样品的枝晶间处易发生点蚀，该处贫Cr，且周围富集C。强化加打磨后的点蚀坑出现在晶界处且深度很浅，无元素偏析现象。结论 LPwC的热载荷可以消除焊缝部位碳化物，减少贫Cr区，提高焊缝的耐腐蚀性能。打磨LPwC强化表面可以进一步提高焊缝的耐腐蚀性能。 |
| 英文摘要: |
| Corrosion wreaks havoc on dissimilar welded joints in the inlet and outlet ports of pressurized water reactors (PWRs) in the first circuit and has become one of the main factors in the development of a large number of cracks before the expiration of the design life. Laser Peening without Coating (LPwC) allows plastic deformation of the surface layer of the material to improve corrosion and has been used by Toshiba in Japan to extend the life of nuclear power plants against corrosion. The work aims to investigate the effect mechanism of LPwC on the corrosion resistance of the weld area of 316L/Inc 600 welded joints. In this study, a 10 mm x 4 mm x 3 mm weld area of 316L/Inc 600 welded joint was used for the study and then polished to a mirror finish with 40 nm silica suspension after ground with metallographic sandpaper (e.g. 400 #, 800 #, 2000 #, and 3000 #). The polished surfaces of the specimens were enhanced by the LPwC enhancement technique. These were two enhancement processes, including 60 mJT1 and 60 mJT1-m. The LPwC-treated specimen was noted as 60 mJT1, and the remelted layer of the other portion of the LPwC-treated specimen was sanded down by 20 µm with 2000 # metallurgical sandpaper and labeled as 60 mJT1-m. Surface roughness was measured with confocal microscopy for both AR and 60 mJT1. The thickness of the remelted layer was measured with an OM microscope. The kinetic potential polarization curves and impedance spectral curves of the specimens with different process parameters in 3.5wt.% NaCl solution were analyzed by an electrochemical workstation to obtain the corrosion resistance of the specimens with different processes, respectively. The corrosion products of the specimens after the electrochemical experiments were washed down by anhydrous ethanol ultrasonication, and the volume and number of pitting pits were measured with a confocal microscope, and the corrosion morphology and elemental distribution were observed with an electron scanning microscope. The results of the experiment showed that LPwC introduced a remelting layer approximately 0.54 μm deep into the metal surface, which increased the surface roughness from 96 nm to 691 nm. After the strengthening and grinding treatment, the charge transfer resistance of the weld increased by 1.7 times and 3.1 times compared to the original state. The passivation current was reduced by 1-2 orders of magnitude, and the pitting voltage increased by more than 100 mV. The mean diameter of pits in the strengthened sample decreased from 33.41 μm to 17.20 μm, and the volume loss decreased from 122 886 μm3 to 49 068 μm3. No element segregation or carbide was observed in the pits. In the original sample, pitting occurred between dendrites, particularly where chromium (Cr) content was low and carbon (C) was enriched around it. After grinding, pits appeared at the grain boundaries, with shallow depth and no element segregation phenomenon. In summary, the thermal load generated by LPwC can eliminate carbides in weld parts, reducing the Cr poor zone and improving the corrosion resistance of the weld. Grinding the surface treated by LPwC can further enhance the corrosion resistance of the weld. |
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