赵青山,宋学平,李来军,曹文辉,柴廷玺.Ni60与NiCr-Cr3C2涂层的机械和热冲击性能对比研究[J].表面技术,2023,52(4):436-445.
ZHAO Qing-shan,SONG Xue-ping,LI Lai-jun,CAO Wen-hui,CHAI Ting-xi.Comparative Study on Mechanical Impact and Thermal Shock Properties of Ni60 and NiCr-Cr3C2 Coatings[J].Surface Technology,2023,52(4):436-445 |
| Ni60与NiCr-Cr3C2涂层的机械和热冲击性能对比研究 |
| Comparative Study on Mechanical Impact and Thermal Shock Properties of Ni60 and NiCr-Cr3C2 Coatings |
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| DOI：10.16490/j.cnki.issn.1001-3660.2023.04.040 |
| 中文关键词: 涂层 HVOF 模具钢 机械冲击 热冲击 |
| 英文关键词:coating HVOF die steel mechanical impact thermal shock |
| 基金项目:甘肃省自然科学基金项目(17JR5RA006);甘肃省高等学校创新能力提升项目(2019A-198);甘肃省高等学校科研项目(2020A-128);甘肃省重点人才项目(2020-0623-RCC-0463) |
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| Author | Institution |
| ZHAO Qing-shan | School of Mechanical Engineering, Lanzhou Petrochemical University of Vocational Technology, Gansu Lanzhou 730060, China |
| SONG Xue-ping | School of Mechanical Engineering, Lanzhou Petrochemical University of Vocational Technology, Gansu Lanzhou 730060, China |
| LI Lai-jun | School of Mechanical Engineering, Lanzhou Petrochemical University of Vocational Technology, Gansu Lanzhou 730060, China |
| CAO Wen-hui | School of Mechanical Engineering, Lanzhou Petrochemical University of Vocational Technology, Gansu Lanzhou 730060, China |
| CHAI Ting-xi | Peili School of Mechanical Engineering, Lanzhou City University, Gansu Lanzhou 730070, China |
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| 中文摘要: |
| 目的 合理选择涂层材料，以提高5CrNiMo热作模具的使用寿命。方法 采用超音速火焰喷涂制备Ni60和NiCr-Cr3C2涂层，对比研究2种粉末所获涂层的微观组织结构、力学性能及机械冲击和热冲击性能。 结果 Cr3C2硬质颗粒可大幅度提高涂层的硬度，在喷涂过程中，Cr3C2硬质颗粒在撞击过程中具有更高的压应力，促进了喷丸效应，使20%NiCr-80%Cr3C2涂层内部及与基体结合界面无明显裂纹。因而，与Ni60涂层相比，20%NiCr-80%Cr3C2涂层具有较高的表面显微硬度(818.9HV)和结合强度(64.04 MPa)。机械冲击试验后，20%NiCr-80%Cr3C2涂层因具有优异的力学性能，被冲击区域的宏观裂纹较少，且未发生明显剥落。2种涂层机械冲击失效的主要机理为高载荷冲击所致的涂层塑性损伤与断裂。由于20%NiCr-80%Cr3C2涂层中存在大量的Cr3C2脆性相，使其同时发生次要的脆性断裂。100次循环热冲击后，2种涂层均未发生剥落，但Ni60涂层表面呈黑蓝色和凹凸不平，表明NiCr-Cr3C2涂层具有更好的抗热冲击能力。结论 20%NiCr- 80%Cr3C2涂层具有更优的微观组织、力学性能、机械冲击和热冲击性能。 |
| 英文摘要: |
| The work aims to improve the service life of hot-work dies (5CrNiMo) by selecting coating material reasonably. Ni60 and NiCr-Cr3C2 coatings were prepared through the supersonic flame spraying technology, and the microstructure, mechanical properties, mechanical impact and thermal shock properties of those coatings were studied. It was found that the two powders were spherical and the particle size ranged from 15 μm to 45 μm, which met the basic requirements of supersonic flame spraying. After spraying, the Ni60 coating had a compact structure without obvious cracks, and the porosity and surface roughness of the coating were 1.05% and 0.106 μm, respectively. However, there were many microcracks at the interface between the coating and matrix. Compared with the Ni60 coating, the porosity and surface roughness of the NiCr-Cr3C2 coating were slightly higher (3.08 % and 0.147 μm, respectively), while there were no obvious cracks in the coating and the interface between NiCr-Cr3C2 coating and the matrix, indicating that the mechanical bite between NiCr-Cr3C2 coating and the matrix was stronger. During the spraying process, Cr3C2 hard particles had higher compressive stress in the impact process, which promoted the shot peening effect. And there was no obvious cracks in the interior of the coating and interface of the 20% NiCr-80% Cr3C2 coating and matrix. Therefore, 20% NiCr-80% Cr3C2 coating had higher surface microhardness (818.9HV) and bonding strength (64.04 MPa) than Ni60 coating (611.1HV and 34.89 MPa, respectively). After the mechanical impact test, the cracks in these two kinds of coatings were basically the same (surface arc crack and transverse crack), and their failure mechanisms were plastic deformation and fracture of the coating caused by high load impact. When the arc crack and transverse crack were connected, spalling failure occurred. From the perspective of coating peeling, the interface between Ni60 coating and matrix produced a lot of cracking, and a large chunk of coating directly peeled off from the matrix, indicating that the failure mechanism of Ni60 coating was the failure of binding force, while the impact surface of NiCr-Cr3C2 coating had only a few peeling holes, indicating that the failure mechanism of NiCr-Cr3C2 coating was cohesion failure. This was mainly due to the presence of a large amount of Cr3C2 brittle phase in 20% NiCr-80% Cr3C2 coating, which caused secondary brittle fracture simultaneously. After 100 cycles of thermal shock experiment, neither of these two coatings peeled off. The oxide layer was generated at the interface between the Ni60 coating and the matrix. Although the oxide layer replaced the microcrack at the interface between the Ni60 coating and the matrix, the bonding between the coating and the matrix was not improved, and it could be found that there were microcracks in the oxide layer. The NiCr-Cr3C2 coating and matrix interface also showed an oxide layer after 100 thermal shock cycle tests, but the oxide layer was continuous and compacted, and combined well with both the matrix and coating, which showed better thermal shock resistance. It was also found that the surface of Ni60 coating was black blue and uneven, which also indicated that NiCr-Cr3C2 coating had better thermal shock resistance. Thus, the 20%NiCr-80%Cr3C2 coating has better microstructure, mechanical properties, mechanical impact and thermal shock properties. |
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