田晓东,孔明,高顺,屈尚坤,周仁健,孙志平.TC4合金表面TiB2强化TiAl3复合渗层的组织形成及耐磨性能[J].表面技术,2021,50(6):258-264.
TIAN Xiao-dong,KONG Ming,GAO Shun,QU Shang-kun,ZHOU Ren-jian,SUN Zhi-ping.Microstructure Formation and Wear Resistance of TiB2-strengthened TiAl3 Composite Coating on TC4 Alloy[J].Surface Technology,2021,50(6):258-264 |
| TC4合金表面TiB2强化TiAl3复合渗层的组织形成及耐磨性能 |
| Microstructure Formation and Wear Resistance of TiB2-strengthened TiAl3 Composite Coating on TC4 Alloy |
| 投稿时间：2020-09-18 修订日期：2021-01-13 |
| DOI：10.16490/j.cnki.issn.1001-3660.2021.06.029 |
| 中文关键词: 钛合金 渗层 硼化物 金属间化合物 耐磨性能 |
| 英文关键词:titanium alloy coating boride intermetallic compound wear resistance |
| 基金项目:大学生创新创业训练项目(S202010710157，S202010710224) |
| 作者 | 单位 |
| 田晓东 | 长安大学 材料科学与工程学院 交通铺面材料教育部工程研究中心，西安 710064 |
| 孔明 | 长安大学 材料科学与工程学院 交通铺面材料教育部工程研究中心，西安 710064 |
| 高顺 | 长安大学 材料科学与工程学院 交通铺面材料教育部工程研究中心，西安 710064 |
| 屈尚坤 | 长安大学 材料科学与工程学院 交通铺面材料教育部工程研究中心，西安 710064 |
| 周仁健 | 长安大学 材料科学与工程学院 交通铺面材料教育部工程研究中心，西安 710064 |
| 孙志平 | 长安大学 材料科学与工程学院 交通铺面材料教育部工程研究中心，西安 710064 |
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| Author | Institution |
| TIAN Xiao-dong | Engineering Research Center of Transportation Materials of Ministry of Education, School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China |
| KONG Ming | Engineering Research Center of Transportation Materials of Ministry of Education, School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China |
| GAO Shun | Engineering Research Center of Transportation Materials of Ministry of Education, School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China |
| QU Shang-kun | Engineering Research Center of Transportation Materials of Ministry of Education, School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China |
| ZHOU Ren-jian | Engineering Research Center of Transportation Materials of Ministry of Education, School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China |
| SUN Zhi-ping | Engineering Research Center of Transportation Materials of Ministry of Education, School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China |
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| 中文摘要: |
| 目的 在TC4钛合金表面制备扩散渗层以提高其耐磨性能。方法 采用包埋渗的方法，首先对TC4合金样品进行950~1100 ℃下4~8 h渗B，然后再进行950~1100 ℃下4 h渗Al制备TiB2强化TiAl3复合渗层。通过分析复合渗层的组织结构、表面粗糙度、硬度和磨损率等，结合对包埋渗B和Al过程的热力学分析，阐明TiB2强化TiAl3复合渗层的组织形成机理和耐磨性能。结果 采用包埋渗的方法，可在TC4钛合金表面制备厚度约37~108 μm的TiB2强化TiAl3复合渗层，其表面粗糙度约为5.485~9.320 μm。复合渗层由硼化物相和Ti-Al金属间化合物相组成，TiAl3层为复合渗层的主体，硼化物主要分布在复合渗层的表层区域，形成TiB2连续层或弥散分布于TiAl3层最外部。通过调整渗Al的温度和时间可调控复合渗层中硼化物的形态和分布。室温干摩擦条件下，TiB2强化TiAl3复合渗层与GCr15对磨时磨损率最低为2.65×10–5 g/(N.m)，较相应渗B层可最多降低约75.0%。结论 可采用扩散渗的方法，在TC4钛合金表面实现TiB2强化TiAl3复合渗层的可控制备，复合渗层表现出了比渗B层更优异的耐磨性能。 |
| 英文摘要: |
| This work aims to prepare diffusion coating on TC4 titanium alloy to improve its wear resistance. By using the method of pack cementation technique, TiB2-strengthened TiAl3 composite coating was prepared through firstly depositing B at 950~1100 ℃ for 4~8 h and then depositing Al at 950~1100 ℃ for 4 h. X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersion spectrum (EDS) and wave dispersion spectrum (WDS) were used to analyze the morphology and structure of the coating. Based on the analysis results of microstructure, surface roughness, hardness and wear rate of the TiB2-strengthened TiAl3 composite coating, combined with the thermodynamic analysis of B and Al deposition processes, the formation mechanism and wear resistance of the TiB2-strengthened TiAl3 composite coating are clarified. The thickness of the TiB2-strengthened TiAl3 composite coating is about 37~108 μm and its surface roughness is about 5.485~9.320 μm. The composite coating is composed of boride and Ti-Al intermetallic compounds. The TiAl3 layer is the main body of the TiB2- strengthened TiAl3 composite coating, and boride phase is mainly distributed on the surface of the composite coating, forming TiB2 continuous layer or dispersing in the outermost part of the TiAl3 layer. The morphology and distribution of borides in the TiB2-strengthened TiAl3 composite coating can be controlled by adjusting the deposition temperature and time of aluminizing. When abrading with GCr15 under the condition of dry friction at room temperature, the wear rate of the TiB2-strengthened TiAl3 composite coating can be as low as 2.65×10–5 g/(N.m), which is reduced by 75.0% compared with the corresponding B deposition layer. The TiB2-strengthened TiAl3 composite coating shows better wear resistance than that of the B deposition layer. |
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