王彦芳,闫晗,李娟,孙胜越,宋增金,石志强.电火花沉积FeCoCrNiCu高熵合金涂层的组织结构与耐蚀性[J].表面技术,2019,48(6):144-149.
WANG Yan-fang,YAN Han,LI Juan,SUN Sheng-yue,SONG Zeng-jin,SHI Zhi-qiang.Microstructure and Corrosion Resistance of FeCoCrNiCu High-entropy Alloy Coating Prepared by Electro-spark Deposition[J].Surface Technology,2019,48(6):144-149 |
| 电火花沉积FeCoCrNiCu高熵合金涂层的组织结构与耐蚀性 |
| Microstructure and Corrosion Resistance of FeCoCrNiCu High-entropy Alloy Coating Prepared by Electro-spark Deposition |
| 投稿时间：2019-03-19 修订日期：2019-06-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2019.06.016 |
| 中文关键词: 电火花沉积 高熵合金 涂层 组织 电化学 |
| 英文关键词:electro-spark deposition (ESD) high-entropy alloy coating microstructure corrosion resistance |
| 基金项目:山东省自然科学基金（ZR2019MEM032）；广西大学广西有色金属及特色材料加工重点实验室开放基金（GXKFJ16-09） |
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| Author | Institution |
| WANG Yan-fang | School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China |
| YAN Han | School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China |
| LI Juan | School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China |
| SUN Sheng-yue | School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China |
| SONG Zeng-jin | School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China |
| SHI Zhi-qiang | School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China |
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| 中文摘要: |
| 目的 通过在45Mn2钢表面进行电火花沉积FeCoCrNiCu高熵合金涂层，改变其表面性能。方法 采用真空吸铸法制备直径为3 mm的FeCoCrNiCu高熵合金电极，采用电火花沉积技术，在45Mn2钢表面制备高熵合金沉积层。通过X射线衍射仪（XRD）、光学显微镜（OM）、扫描电子显微镜（SEM）等分析研究沉积层的相组成、表面形貌、表面粗糙度和显微组织。通过三电极体系对涂层进行极化曲线和电化学阻抗谱（EIS）测试，分析其在3.5%NaCl溶液中的电化学腐蚀行为。结果 制备的FeCoCrNiCu涂层连续、均匀，具有简单的FCC结构，表面呈银灰色橘皮状，厚度约为25 μm。涂层表面凸凹不平，为典型的“溅射状”花样形貌，表面粗糙度均方根偏差Rq约为4 μm。极化曲线表明，高熵沉积层自腐蚀电位为-0.548 V，较45Mn2基材正移约180 mV，腐蚀电流密度为1.59 μA/cm2，约为基材的1/6。电化学阻抗谱EIS测试结果显示，FeCoCrNiCu高熵合金沉积层较45Mn2基材具有更大的容抗弧半径和极化电阻，其模拟电路可以用R(Q(R(QR)))表示。结论 电火花沉积技术是一种极具发展潜力的高熵合金涂层制备技术，制备的FeCoCrNiCu高熵合金涂层可有效提高基材的耐蚀性能。 |
| 英文摘要: |
| The work aims to deposit FeCoCrNiCu high-entropy alloy coating on 45Mn2 steel to improve the surface proper-ties. FeCoCrNiCu high-entropy alloy rod with a dimeter of 3 mm was prepared by copper mold suction casting and the FeCoCrNiCu high-entropy alloy coating was deposited on 45Mn2 steel surface by electro-spark deposition technique. The phase composition, surface morphologies and microstructures of the deposited coatings were analyzed by optical microscope (OM), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The electrochemical corrosion behaviors of the deposited coating in 3.5%NaCl were measured by polarization curves and electrochemical impedance spectroscopy. The prepared FeCoCrNiCu coating was continuous and uniform with a simple FCC structure. The surface was silver-gray orange peel and about 25 μm thick. The surface of the coating was uneven and showed typical "sputtering" pattern. The root mean square deviation (Rq) of the surface roughness was about 4 μm. The polarization curves showed that the self-corrosion potential of the high-entropy deposits was -0.548 V, which was 180 mV higher than that of 45Mn2 substrates, and the corrosion current density was 1.59 μA/cm2, which was about 1/6 of that of the substrates. The EIS results of electrochemical impedance spectroscopy showed that the FeCoCrNiCu high-entropy alloy deposit had larger capacitive arc radius and polarization resistance than 45Mn2 substrate, and the analog circuit could be expressed by R(Q(R(QR)). Electro-spark deposition (ESD) is a promising technology for preparing high-entropy alloy coatings. The high-entropy FeCoCrNiCu coating prepared can effectively improve the corrosion resistance of the substrate. |
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