贾静焕,刘智勇,杜翠薇,李晓刚.316L 不锈钢在高 pH 碱性硫化物环境中的应力腐蚀行为[J].表面技术,2015,44(3):36-40,56. JIA Jing-huan,LIU Zhi-yong,DU Cui-wei,LI Xiao-gang.Stress Corrosion Behavior of 316L Stainless Steel in High-pH Alkaline Sulphide Solution[J].Surface Technology,2015,44(3):36-40,56 |
316L 不锈钢在高 pH 碱性硫化物环境中的应力腐蚀行为 |
Stress Corrosion Behavior of 316L Stainless Steel in High-pH Alkaline Sulphide Solution |
投稿时间:2014-11-14 修订日期:2015-03-20 |
DOI:10.16490/j.cnki.issn.1001-3660.2015.03.006 |
中文关键词: 316L 不锈钢 碱性溶液 硫化物 应力腐蚀 |
英文关键词:316L stainless steel alkaline solution sulphide stress corrosion |
基金项目:国家高技术研究发展计划(863 计划,2012AA040105);国家自然科学基金(51471034);北京市青年英才计划资助 |
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Author | Institution |
JIA Jing-huan | 1. Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China;2. Key Laboratory of Corrosion and Protection of Ministry of Education, Beijing 100083, China |
LIU Zhi-yong | 1. Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China;2. Key Laboratory of Corrosion and Protection of Ministry of Education, Beijing 100083, China |
DU Cui-wei | 1. Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China;2. Key Laboratory of Corrosion and Protection of Ministry of Education, Beijing 100083, China |
LI Xiao-gang | 1. Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China;2. Key Laboratory of Corrosion and Protection of Ministry of Education, Beijing 100083, China |
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中文摘要: |
目的 研究 316L 不锈钢在碱性硫化物溶液中的应力腐蚀行为,为其在碱性环境中的适用性提供参考依据。 方法 采用动电位极化曲线、电化学阻抗(EIS)测量技术、慢应变速率拉伸试验(SSRT)、U形弯试样浸泡试验以及 SEM 腐蚀形貌分析方法。 结果 316L 不锈钢试样在碱性硫化物溶液中具有较低的应力腐蚀(SCC)敏感性,腐蚀机理主要为阳极溶解型,且 SCC 敏感性随着 pH 升高而降低。 结论316L 不锈钢试样在碱性 NaCl/ Na2S 溶液中虽然表现出应力腐蚀特征,但敏感性较低,适用于该实验模拟的碱性溶液中。 |
英文摘要: |
Objective To study the stress corrosion cracking (SCC) behavior of 316L stainless steel in alkaline sulphide solution, and to provide reference for its applicability in alkaline environment. Methods Potentiodynamic polarization, electrochemical impedance spectrums (EIS), slow strain rate test(SSRT), U type bending immersion test and superficial analysis technique using scanning electron microscope (SEM) were applied. Results 316L stainless steel had relatively low SCC susceptibility in alkaline sulphide solution, and the main corrosion mechanism was anodic dissolution (AD). The SCC susceptibility decreased with the increase of pH value. Conclusion Although 316L stainless steel showed features of stress corrosion in alkaline NaCl/ Na2S solution, the SCC sensitivity was low, so it was suitable for the simulated alkaline solution in the experiment. |
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