周小平,王小军,朱理奎.反应等离子喷涂 Al2O3-TiB2-Al 复相涂层的反应机理[J].表面技术,2014,43(4):6-10,16.
ZHOU Xiao-ping,WANG Xiao-jun,ZHU Li-kui.Reaction Mechanism of the Formation of Plasma-spraying Al2 O3-TiB2 -Al Composite Coatings[J].Surface Technology,2014,43(4):6-10,16
反应等离子喷涂 Al2O3-TiB2-Al 复相涂层的反应机理
Reaction Mechanism of the Formation of Plasma-spraying Al2 O3-TiB2 -Al Composite Coatings
投稿时间:2014-02-21  修订日期:2014-04-09
DOI:
中文关键词:  反应等离子喷涂  Al2O3-TiB2-Al 复合涂层  燃烧波淬熄试验  燃烧反应
英文关键词:reactive plasma spraying  Al2O3-TiB2-Al composite coatings  combustion front quenching technique  combustion reaction
基金项目:国家自然科学基金(51171062)
作者单位
周小平 湖北工业大学 绿色轻工材料湖北省重点实验室, 武汉 430068 
王小军 湖北工业大学 绿色轻工材料湖北省重点实验室, 武汉 430068 
朱理奎 湖北工业大学 绿色轻工材料湖北省重点实验室, 武汉 430068 
AuthorInstitution
ZHOU Xiao-ping Reaction Mechanism of the Formation of Plasma-spraying Al2 O3-TiB2 -Al Composite CoatingsHubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068,China 
WANG Xiao-jun Reaction Mechanism of the Formation of Plasma-spraying Al2 O3-TiB2 -Al Composite CoatingsHubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068,China 
ZHU Li-kui Reaction Mechanism of the Formation of Plasma-spraying Al2 O3-TiB2 -Al Composite CoatingsHubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068,China 
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中文摘要:
      目的 在铝合金表面制备 Al2O3-TiB2-Al 复合涂层,研究 Al,TiO2,B2O3 在等离子喷涂中的反应机理。 方法 采用反应等离子喷涂技术在铝合金表面制备复合涂层,应用扫描电镜与 X 射线衍射技术测试复合涂层的物相组成和显微组织,并通过燃烧波淬熄试验分析等离子喷涂产物。 结果 机械球磨可以有效降低粉末发生反应的活化能,等离子喷涂最佳飞行距离范围为 150 ~ 200 mm。 结论 喷涂粉末在飞行过程中发生反应,经历了预热、熔化、分解、团聚等过程,验证了最终引燃发生燃烧化学反应的机理。
英文摘要:
      Objective To investigate the preparation of Al2O3 -TiB2 -Al composite coating on the aluminum alloy surface, and analyze the reaction mechanism of Al, TiO2, B2O3in plasma spraying. Methods The composite coating was prepared on the surface of aluminum alloy using plasma spraying technology. The phase composition and microstructure evaluation of composite coating layer were analyzed by scanning electron microscopy ( SEM) and X-ray diffraction technology. The combustion products of combustion front quenching technique were tested. Results It was found that the activation energy of the powder reaction was effectively decreased by mechanical milling, and the optimal flying distance range of plasma spraying was 150 ~ 200 mm. Conclusion According to the results, the composite powder experienced the processes of preheating, melting, decomposition and agglomeration during the flight, which verified the mechanism of combustion reaction.
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