张玉萍,武志红,鞠鹤,蔡天晓,方媛.铱涂覆量对IrO2-Ta2O5钛阳极性能的影响[J].表面技术,2010,39(4):33-35. ZHANG Yu-ping,WU Zhi-hong,JU He,CAI Tian-xiao,FANG Yuan.Effect of Coating Quantity of Ir on Properties of IrO2-Ta2O5Titanium Anode[J].Surface Technology,2010,39(4):33-35 |
铱涂覆量对IrO2-Ta2O5钛阳极性能的影响 |
Effect of Coating Quantity of Ir on Properties of IrO2-Ta2O5Titanium Anode |
投稿时间:2010-05-26 修订日期:2010-08-10 |
DOI: |
中文关键词: IrO2-Ta2O5 铱涂覆量 钛阳极 |
英文关键词:IrO2-Ta2O5 coating quantity of Ir titanium anode |
基金项目:国家科技人员服务企业资助项目(2009GJG00044) |
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Author | Institution |
ZHANG Yu-ping | Taijin Industrial Electrochemical Technology Co Ltd,Northwest Institute for Nonferrous Metal Research, Xi'an 710016, China |
WU Zhi-hong | Materials Science and Engineering College, Xi'an University of Architecture& Technology, Xi'an 710061, China |
JU He | Taijin Industrial Electrochemical Technology Co Ltd,Northwest Institute for Nonferrous Metal Research, Xi'an 710016, China |
CAI Tian-xiao | Taijin Industrial Electrochemical Technology Co Ltd,Northwest Institute for Nonferrous Metal Research, Xi'an 710016, China |
FANG Yuan | Taijin Industrial Electrochemical Technology Co Ltd,Northwest Institute for Nonferrous Metal Research, Xi'an 710016, China |
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中文摘要: |
测试了不同铱涂覆量的IrO2-Ta2O5钛阳极的表面形貌、强化寿命及析氧极化曲线。结果表明:铱涂覆量5 g/m2和10 g/m2的涂层形貌呈无规则粉状堆积;铱涂覆量达到20 g/m2时,涂层表面出现了枝状结构;铱涂覆量达到30 g/m2时,这种枝状结构已经很明显。IrO2-Ta2O5钛阳极涂层中铱涂覆量在5~ 30 g/m2范围内,随铱涂覆量的增加,阳极强化寿命增加得较快;当铱涂覆量超过30 g/m2,随铱涂覆量的增加,阳极强化寿命增幅减小。铱涂覆量对IrO2-Ta2O5钛阳极析氧的电催化活性影响不大。 |
英文摘要: |
Surface morphologies,accelerated life,and polarization curves for oxygen evolution of IrO2-Ta2O5titanium anode with different Ir coating were tested and analyzed. The results show that morphologies of the anode sarface coated 5 g/m2 and 10 g/m2 Ir are irregular powder accumulation, morphology of the anode surface coatd 20 g/m2 Ir exhibits branch structure,and morphology of the anode surface coatd 30 g/m2 Iris obvious branch structure.Anode accelerated life increases fast with the content quantity of Irincreasing when it is in the range of 5~ 30 g/m2, anode accelerated life increases slowly with the coating quantity of Ir increasing when it exceeds 30 g/m2. The content quantity of Ir has little effect on electrocatalytic activity for oxygen evolutiont reaction of IrO2-Ta2O5titaium anode. |
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