夏先朝,聂敬敬,李逸,蔡微波,孙京丽,袁勇,张利嵩,王晓雪,董泽华.镁合金超疏水磷酸盐化学转化涂层的制备与耐蚀性能[J].表面技术,2024,53(16):116-128.
XIA Xianchao,NIE Jingjing,LI Yi,CAI Weibo,SUN Jingli,YUAN Yong,ZHANG Lisong,WANG Xiaoxue,DONG Zehua.Preparation and Corrosion Resistance of Superhydrophobic Phosphate Chemical Conversion Coatings for Magnesium Alloys[J].Surface Technology,2024,53(16):116-128 |
| 镁合金超疏水磷酸盐化学转化涂层的制备与耐蚀性能 |
| Preparation and Corrosion Resistance of Superhydrophobic Phosphate Chemical Conversion Coatings for Magnesium Alloys |
| 投稿时间：2023-09-05 修订日期：2024-01-11 |
| DOI：10.16490/j.cnki.issn.1001-3660.2024.16.009 |
| 中文关键词: 镁合金 耐蚀性 表面防护 化学转化 超疏水涂层 |
| 英文关键词:Mg alloys corrosion resistance surface protection chemical conversion superhydrophobic coating |
| 基金项目:上海航天精密机械研究所自主研发项目 |
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| Author | Institution |
| XIA Xianchao | Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China;School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China |
| NIE Jingjing | Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China |
| LI Yi | Shanghai Academy of Spaceflight Technology, Shanghai 201109, China |
| CAI Weibo | Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China |
| SUN Jingli | Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China |
| YUAN Yong | Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China |
| ZHANG Lisong | Beijing Institute of Space Long March Vehicle, Beijing 100076, China |
| WANG Xiaoxue | Beijing Institute of Space Long March Vehicle, Beijing 100076, China |
| DONG Zehua | School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China |
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| 中文摘要: |
| 目的 研究超疏水改性处理对磷酸盐化学转化涂层耐蚀性的影响，利用PA和Ce3+的螯合作用及低表面能物质的修饰提升涂层的防护性能。方法 将仿生超疏水技术和化学转化技术相结合，对传统的磷酸盐化学转化膜进行后处理改性，在镁合金基体上制备了具有超疏水效应的磷酸盐化学转化膜。通过扫描电子显微镜、红外光谱、接触角测试、电化学测试等方法研究改性后涂层的微观形貌、润湿性和耐蚀性。结果 SEM结果显示，经过后处理改性后，磷酸盐化学转化膜(PCC)表面的缺陷被有效封堵，膜层致密性显著提高。接触角测试结果表明，改性后膜层的静态水接触角高达156.5°，滚动角低至5°，呈现出优异的超疏水性能。电化学测试结果显示，后处理改性后的超疏水膜层的防护性能显著提高;相较于PCC膜层，超疏水膜层的腐蚀电流密度降低了1个数量级，低频阻抗模值则提高了1个数量级，并且经过12 d浸泡后其低频阻抗模值仍然高于104 Ω.cm2。中性盐雾测试结果表明，改性后涂层的耐盐雾性能大幅提升，耐盐雾超过100 h。结论 该涂层展现出了优异的憎水性能和良好的自清洁性能，能够为基体提供高效且持久的腐蚀防护。 |
| 英文摘要: |
| Magnesium (Mg) alloys are promising materials for a number of applications in aviation, spaceflight, high- speed rail and automotive industry due to their combination of light weight, excellent shock absorption and recyclability. However, the relatively high corrosion susceptibility of Mg alloys seriously restricts their widespread use. Use of reliable surface protection coatings is an effective method to prolong the service life of Mg alloys and break through the bottleneck of Mg alloy application. Phosphate conversion coatings (PCC) stand out among lots of surface protection technologies for Mg alloys due to its advantages of simplicity, high efficiency and green environmental protection. However, the defects and micro-cracks on the surface of PCC provide a permeable path for water and aggressive ions in a corrosive environment, thus seriously weakening the corrosion protection ability of PCC. Earlier studies have focused on improving the density of PCC by optimizing the process, but in practice the effect on enhancing the durability of PCC is not satisfactory. At present, the construction of high corrosion resistance coatings by integrating PCC with other surface treatment technologies is a research hotspot in the field of Mg alloy corrosion protection. |
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